节点文献

配合物[Ni（phen）₃][（C₆H₅）₂C（OH）COO]₂·6H₂O的合成、晶体结构及电化学性质

Synthesis, Crystal Structure and Electrochemical Properties of Complex [Ni（phen）₃][（C₆H₅）₂C（OH）COO]₂·6H₂O

推荐 CAJ下载
PDF下载
不支持迅雷等下载工具，请取消加速工具后下载。

【Author】 YANG Ying-Qun1,2 LI Chang-Hong3 KUANG Dai-Zhi*,1 GUO Dong-Cai2 CHEN Zhi-Min1 CHEN Man-Sheng1 KUANG Yun-Fei1 (1Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008) (2College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082) (3Department of Chemical Engineering, Hunan University Hengyang Branch, Hengyang, Hunan 421101)

【机构】衡阳师范学院化学与材料科学系；湖南大学衡阳分校化学化工系；湖南大学化学化工学院；衡阳师范学院化学与材料科学系衡阳421008湖南大学化学化工学院；长沙410082；衡阳421101；衡阳421008；

【Abstract】 The title complex with benzilic acid and 1,10-phenanthroline monohydrate has been synthesized and characterized in the solvent mixture of water and methyl-alcohol. It falls into the triclinic, characteristic of the space group P1 with a=1.142 8(3) nm, b=1.638 8(4) nm, c=1.645 6(4) nm, α=74.428(5)°, β=84.205(5)°, γ=74.917(5)°, V=2.864 9(12) nm3, Dc=1.347 g·cm-3. Z=2, F(000)=1 216, the reliability factor R1=0.068 9, wR2=0.189 9. The crystal structure shows that the nickel atom is coordinated with six nitrogen atoms from the three phens, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 274184.更多还原