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新型金属杂冠醚配合物18-MC-6[Mn6(4-Amashz)6(DMF)6]·12DMF的合成
Synthesis of a Novel Metallacrown 18-MC-6[Mn6(4-Amashz)6(DMF)6]·12DMF
【摘要】 合成了一种新型金属杂冠醚配合物[Mn6(4-amashz)6(DMF)6].12DMF,并用X射线衍射法对其结构进行了表征.研究了该化合物修饰金电极催化氧还原的性质,结果表明,该化合物具有平面碟状结构,对在碱性溶液中的氧有显著的催化还原作用.
【Abstract】 A new macrocyclic manganese 18-azametallacrown-6 compound with the formula \·12DMF was synthesized,and the structure was characterized by X-ray diffraction(analysis.) The property of electrocatalytic reduction of dioxygen was also studied.The results indicate that the multinuclear compound is disk-shaped and has an obvious electrocatalytic reduction of dioxygen in base.
【关键词】 金属杂冠醚;
单晶;
电催化氧还原;
【Key words】 metallacrown; single crystal; electrocatalytic reduction of dioxygen;
【Key words】 metallacrown; single crystal; electrocatalytic reduction of dioxygen;
【基金】 国家自然科学基金资助项目(20171035)
- 【文献出处】 武汉大学学报(理学版) ,Journal of Wuhan University(Natural Science Edition) , 编辑部邮箱 ,2006年06期
- 【分类号】O641.4
- 【被引频次】5
- 【下载频次】133