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表面活性剂辅助水热合成氧化锌纳米棒

Preparation of ZnO Nanorods via Surfactant Assisted Hydrothermal Synthesis

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【作者】 储德韦曾宇平江东亮

【Author】 CHU De-Wei, ZENG Yu-Ping, JIANG Dong-Liang ( Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China; Graduate School of the Chinese Academy of Sciences, Beijing 100049, China)

【机构】 中国科学院上海硅酸盐研究所中国科学院上海硅酸盐研究所 上海 200050 中国科学院研究生院北京 100049上海 200050

【摘要】 以碱式碳酸锌为前驱体,十六烷基三甲基溴化铵为表面活性剂,在乙醇-水体系中水热反应制备了直径在10nm以下的氧化锌纳米棒.用XRD、TEM、SAED等分析手段对制备的粉体进行了表征,并对粉体的室温光致发光性能进行了测试.结果表明,合成的氧化锌纳米棒结晶良好,沿[001]方向生长,具有良好的近紫外发光性能.同时对氧化锌纳米棒的生长机制进行了探讨.

【Abstract】 By using Zn4CO3(OH)6·H2O as the precursor, cetyltrimethyl ammonium bromide (CTAB) as the surfactant, ZnO nanorods with several nanometer diameters were synthesized. The product was characterized by means of X-ray powder diffraction (XRD), transmission electron microscope (TEM) and selected area electron diffraction (SAED). Its room-temperature photolu-minescence properties were also studied. The results show that the as-prepared products have high crystallinity and grow along the [001] direction, combining with good near UV emission properties. The mechanism for the ZnO nanorod growth was also discussed.

【关键词】 氧化锌纳米棒水热法
【Key words】 zinc oxidenanorodshydrothermal
  • 【文献出处】 无机材料学报 ,Journal of Inorganic Materials , 编辑部邮箱 ,2006年03期
  • 【分类号】O614.241
  • 【被引频次】45
  • 【下载频次】1374
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