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超支化树脂的合成及在聚氨酯涂料中的应用

Preparation of hyperbranched resin and its applications in matt topcoating

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【作者】 王延飞沈本贤荆红德

【Author】 WANG Yan-fei~(1,2),SHEN Ben-xian~1,JING Hong-de~2(1.East China University of Science and Technology,Shanghai 200237,China;2.Guangdong Huarun Paint Chemical Co.,Ltd.,Shunde 528306,China)

【机构】 华东理工大学化工学院广东华润涂料有限公司博士后工作站 上海200237广东华润涂料有限公司博士后工作站广东顺德528306上海200237

【摘要】 以超支化聚合物作为基料与脂肪酸等单体合成了超支化树脂,并利用红外光谱,GPC等仪器对超支化树脂进行表征;同时研究了超支化树脂在聚氨酯哑光面漆中的应用,研究表明:实验所制备的超支化树脂虽然消光效果较差,但是采用超支化树脂部分代替商业哑光树脂可以改善漆膜的透明性及耐冲击性。

【Abstract】 Hyperbranch resin was synthesized based upon hyperbranched polymer and aliphatic and /or aromatic acids.Its structure was characterized by Fourier transform infrared spectroscopy(FTIR) and GPC and its application in matt topcoats was investigated.It was showed hyperbranched polyester was more than commercial resinous polyols in impact resistance and transparency of matt topcoating film,and its extinction was worse.But partial replacement of commercial resinous polyols with hyperbranched polyester could result in market improvement in transparency and impact resistance of matt topcoating.

【基金】 国家星火计划资助项目(2005EA780062)
  • 【分类号】TQ633
  • 【被引频次】2
  • 【下载频次】268
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