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粘土或纳米碳酸钙填充聚合物的结晶性能和流变行为研究

Study on crystallization and rheology of polymer filled with clay or nano-CaCO3

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【作者】 古菊贾德民罗远芳程时

【Author】 GU Ju,JIA De-min,LUO Yuan-fang,CHENG Rong-shi(College of Materials Science and Engineering,South China University of Science and Technology,Guangzhou 510641,China)

【机构】 华南理工大学材料科学与工程学院华南理工大学材料科学与工程学院 广东广州510641广东广州510641

【摘要】 总结了粘土、纳米碳酸钙填充聚合物的结晶性能和流变行为,阐述了无机纳米填料对聚合物复合材料结晶性能和流变行为的影响,同时论述了结晶性能和流变行为与纳米复合材料力学性能及加工性能的关系。结果表明,粘土和纳米碳酸钙对结晶聚合物均有异相成核剂的作用,在基本保持聚合物强度的同时,明显改善复合材料的韧性,同时保持材料原有的加工性能。

【Abstract】 The crystallization and rheology of polymer filled with clay or nano-CaCO3 were summarized.The effects of polymer filled with inorganic nano-filler were expounded.The relationship between crystallization,rheology and mechanical properties,processing of nanocomposite was discussed.The results showed clay and nanoCaCO3 were effective nucleating agent for crystal polymer.The strength was invariable on the whole and the toughness of nanocomposite was obviously improved by loading clay or nano-(CaCO3,)in the mean time,the nanocomposite held the processing of original polymer.

【基金】 国家自然科学基金资助项目(50572021)
  • 【分类号】TQ317
  • 【被引频次】5
  • 【下载频次】410
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