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制备方法对BaAl12O19-α催化剂结构和甲烷催化燃烧活性的影响

Effect of Preparation and Mn2+ Substituted on the Crystal Structure and Catalytic Activity of BaAl12O19-αfor Catalytic Combustion of Methane

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【作者】 朱安民宋永吉任晓光陈霭璠罗瑞贤

【Author】 ZHU An-min~(1,2),SONG Yong-ji~2,REN Xiao-guang~2,CHEN Ai-fan~1,LUO Rui-xian~1(1.Beijing University of Chemical Technology,Beijing 10029,China;2.Beijing Institute ofPetrochemical Technology,Beijing 102617,China)

【机构】 北京化工大学北京石油化工学院北京化工大学 北京100029北京102617北京100029

【摘要】 采用反相微乳液法、普通氨水共沉淀法制备BaAl12O19-α六铝酸盐催化剂及其中的Al3+部分被Mn2+取代的BaMnAl11O19-α催化剂,研究了合成方法、Mn2+取代部分Al3+对催化剂晶相结构、比表面积、粒径以及甲烷催化活性的影响。结果表明,反相微乳液法制备的催化剂经1200℃焙烧后更有利于形成六铝酸盐晶相,且具有粒径小、比表面积大、甲烷催化活性高的特点。与BaAl12O19-α相比,BaMnAl11O19-α催化剂具有更高的比表面积(42.87m2/g)和更优异的催化活性,起燃温度T10%为473℃,T90%为668℃。

【Abstract】 The catalysts for catalytic combustion of methane,hexa-aluminate BaAl12O19-αand its derivtive,BaMnAl11O19-α,in which Mn2+ partially substituted for Al3+,were prepared by reverse microemulsion mediated NH4OH coprecipitation and conventional NH4OH coprecipitation methods.Effects of preparation methods and Mn2+ substitution on the phase structure,surface area,diameters of catalysts and catalytic combustion of methane were investigated.The results show that the catalysts prepared by reverse microemulsion mediated NH4OH coprecipitation forms hexa-aluminate crystal phase more easily when calcined at 1200℃,and has smaller particle size,larger specific surface area and higher catalytic activity than the catalyst prepared by conventional NH4OH coprecipitation method.Compared to unsubstituted catalyst,Mn2+ substituted catalyst had higher specific surface area(42.87m2/g)and more excellent catalytic activity for methane combustion,and the temperatures at which 10% and 90% methane were converted were 473℃ and 668℃,respectively.

【基金】 国家自然科学金资助项目(20476012);北京市自然科学基金资助项目(8032007);北京市属、市管高校人才强教计划资助项目—清洁燃料技术开发(BJJ WR20051102)
  • 【文献出处】 天然气化工 ,Natural Gas Chemical Industry , 编辑部邮箱 ,2006年05期
  • 【分类号】O643.3
  • 【被引频次】11
  • 【下载频次】143
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