【摘要】 用乙二胺与乙酰丙酮、水杨醛反应合成了一种异双四齿席夫碱配体(H2L)及其铜、钴、镍、锌配合物,通过元素分析、红外光谱、紫外光谱、X射线光电子能谱等手段对配体及其配合物进行了结构表征.结果表明,推测所有配合物均为烯醇式四配位结构,确定新配合物的组成为MC14H16N2O2(M=Cu,Co,Ni,Zn).研究了配合物对双氧水的催化分解性能.更多还原

【Abstract】 An unsymmetrical tetradentate Schiff base ligand（H₂L） and its copper（Ⅱ）,cobalt（Ⅱ）,nickel（Ⅱ） and zinc（Ⅱ） complexes have been synthesized employing the reaction of ethylenediamine,acetylacetone and salicylaldehyde,and characterized by elemental analysis,IR,UV-VIS and XPS respectively.Based on the experimental results,a four-coordinated enol model was proposed for these complexes.The composition of new coordination compounds is MC₁₄H₁₆N₂O₂（M=Cu,Co,Ni,Zn）.The catalysis properties of these complexes for decomposition of hydrogen peroxide has been studied.更多还原