【摘要】 通过溶剂热合成法制备一种新的化合物Cd(DPPZ)2Cl2,并通过X射线单晶衍射仪对其进行了表征.单晶分析表明:化合物属于单斜晶系,C2/C空间群,a=0.84836(17)nm,b=1.2615(3)nm,c=2.9178(6)nm,α=90.00°,β=92.774(4)°,γ=90.00°,V=3.1191(11)3,Z=4,T=293(2)K,Dc=1.197 cm-1,μ=1.434mm-1,R1=0.01497,wR2=0.3702.更多还原

【Abstract】 A novel coordination polymer [Cd（DPPZ）₂Cl₂]n was prepared by hydrothermal synthesis and characterized by single-crystal X-ray diffraction.Single crystal X-ray analysis indicates that this compound crystallizes in monoclinic system,space group C2/c with parameters:a=0.84836（17） nm,b=1.2615（3） nm,c=2.9178（6） nm,α=90.00°,β=92.774（4）°,γ=90.00°,V=3.1191（11） ?3,Z=4,T=293（2） K,D_c=1.197 cm^-1,μ=1.434 mm^-1,R₁=0.01497,wR₂=0.3702.更多还原