【摘要】 用混合溶剂法合成了带有活性基团的四(3-甲氧基-4-羟基苯基)卟啉,考察了催化剂、溶剂的配比、反应温度、反应时间等因素对反应产率的影响,确定了合适的反应条件:V(丙酸)∶V(冰醋酸)∶V(硝基苯)=2∶2∶1;反应温度:120~140℃;反应时间:50~60min。还利用IR,UV-VIS,热分析,1HNMR数据对配合物的结构进行了表征。更多还原

【Abstract】 In this paper,tetrakis tetrakis（3-methoxy-4-hydroxyphenyl） porphyrin were synthesized and characterized by IR,UV-VIS,TG-DTA and（）¹H NMR. The reaction conditions were studied by using different types of catalyst,ratio of solvents and reaction temperature,etc.The optimised condition was a reaction time of 50-60 min at 120-140℃ using 2:2:1 of propionic acid: acetic acid: nitrobenzene.更多还原