【摘要】 以乙酸锌、正丁胺及水杨醛为原料在甲醇介质中反应,合成得到了席夫碱配合物N-亚水杨基正丁胺锌[Zn(CH3CH2CH2CH2N=CHC6H4O)2],用元素分析、红外光谱、核磁共振氢谱和热重分析进行了谱学表征,培养了该配合物的单晶,并通过单晶X射线衍射测得其晶体结构为四方晶系,空间点群为P-4,a=1.4380(2)nm,b=1.4380(2)nm,c=0.53803(18)nm,α=β=γ=90°,V=1.1126(4)nm3;Dc=1.247 g/cm3;Z=2;F(000)=400;μ=1.12mm-1。锌离子位于变形四面体的中心,分别与两个席夫碱N原子和两个酚氧负离子形成配合物。更多还原

【Abstract】 A new complex [Zn（CH₃CH₂ CH₂CH₂N=CHC₆H₄O）₂]¹ was synthesized based on the reaction of zinc（II） acetate,salicylal and n-butylamine in methanol medium.The structure of the complex was confirmed by IR,¹H NMR,elemental analysis and thermal analysis.The crystal structure of the complex was also determined by X-ray single crystal diffraction.The crystal belongs to tetragonal system with space group P-4,and crystallographic data of the compound are: a=1.4380（2）nm,b=（1.4380（2）nm）,c=0.53803（18）nm,α=β=γ=90°,V=1.1126（4）nm³;D_c=1.247g/cm³;Z=2;F（000）=400;μ=1.12mm^-1.Zinc（Ⅱ） atom lies at the center of a distorted tetrahedral coordination consisting of two N atoms and two O atoms from two schiff bases.更多还原