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碱酶结合脱毛法在牦牛皮上的应用(Ⅰ)

A Paint Unhairing of Lower Sulfide Associated with Enzyme for Yak Hide(Ⅰ)

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【作者】 李胜利陈武勇李慧陈田

【Author】 LI Sheng-li,CHEN Wu-yong~*,LI Hui,CHEN Tian(Key Laboratory of Leather Chemistry and Engineering(Sichuan University),Ministry of Education,Chengdu 610065,China)

【机构】 皮革化学与工程教育部重点实验室(四川大学)皮革化学与工程教育部重点实验室(四川大学) 四川成都610065四川成都610065

【摘要】 采用碱酶(一种碱性蛋白酶、碱性脂肪酶和糖化酶的复合酶)结合脱毛法,目的是降低牦牛皮脱毛工序中硫化钠的用量。在实验中,首先分析硫化钠的浓度和酶的用量对牦牛皮脱毛的影响,然后通过碱酶结合脱毛的实验得到了牦牛皮脱毛液的最适配方:以皮重为基准,按照通常的涂灰量0.2 g/g皮,温度20℃,脊背部位为硫化钠的质量浓度30~35 g/L,酶的用量0.3%;边腹部位为硫化钠的浓度15~20 g/L,酶的用量0.2%。此方法脱毛时间为12~14 h,脱毛干净,粒面层完好,无残留毛根。与传统的脱毛液中硫化钠的质量浓度(脊背部位60~65 g/L,边腹部位为30~35 g/L[1])相比,此方法可使硫化钠的质量浓度降低约50%,大大降低了硫化物的污染程度。

【Abstract】 A Lower concentrationof sodium sulfide associatedwith the complex enzyme was studied for reducing the amount of sulfide in the paint unhairing of yak hide.The effects of unhairing with different concentrations of sodium sulfide and various amount of the enzyme were firstly evaluated.Then,the optimum prescription was obtainedby the experiment of combination sodium sulfide and enzyme.As usual amount of 20% based on the weight of hide,thedifferent area on the hide was painted with differentpaste.The better concentration of sodium sulfide is 30-35 g/L for back area and 15-20 g/L for belly.Also,the appropriateamount of the complex enzyme based on the weight of hide is 0.3% for back and 0.2% for belly. After the paste waspainted on the hide for 12 hours,all of the hairs could be cleaned up and there are not any residualhair rootsin the grain Layer.Compared with the traditional unhairing process,this method could make 50% of the sodium sulfide off,sothe impact of sulfide on environmentmay effectively decrease.

【关键词】 制革脱毛牦牛皮硫化钠
【Key words】 leatherunhairingyak hidesodium sulfideenzyme
【基金】 国家环保总局项目(项目编号:ZXZB-0554L05)
  • 【文献出处】 皮革科学与工程 ,Leather Science and Engineering , 编辑部邮箱 ,2006年04期
  • 【分类号】TS54
  • 【被引频次】14
  • 【下载频次】276
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