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环丙烷双酰肼类杀虫剂的设计与合成

Synthesis and insecticidal activity of cyclopropane diacylhydrazines

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【作者】 苏江涛李早英胡先明孔繁蕾

【Author】 SU Jiang-tao1, LI Zao-ying1, HU Xian-ming2, KONG Fan-lei3 (1.Chemistry and Molecule Science College, Wuhan University, Wuhan 430072, China; 2.College of Pharmacy, Wuhan University, Wuhan 430072, China; 3.Jiangsu Agrochem Laboratory, Changzhou 213022, Jiangsu, China)

【机构】 武汉大学化学与分子科学学院武汉大学药学院江苏省农用激素工程技术研究中心 武汉430072武汉430072江苏常州213022

【摘要】 以结构上有可比性的环丙烷羧酸为原料,合成了环丙烷双酰肼化合物,结构经红外和核磁验证。生物活性测定结果表明,在250mg/L的浓度下,化合物1,1’-二羧酸乙酯偕二甲基环丙烷双酰肼对蚕豆蚜虫有较好杀虫活性。

【Abstract】 Diacylhydrazine cyclopropane compounds were synthesized from cyclopropanecarboxylic acids which have comparable characters in the structures. Their structures were confirmed by IR spectrum and 1H NMR. Biologi- cal activity of the compounds were studied and the result indicated that the compound 1,1’-ethyl dicarboxylate gem- dimethyl-cyclopropanediacylhydrazine has good activity against bean aphidsin at 250mg/L.

【关键词】 环丙烷双酰肼合成杀虫活性
【Key words】 cyclopropanediacylhydrazinesynthesisinsecticide activity
  • 【分类号】TQ453.2
  • 【被引频次】14
  • 【下载频次】389
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