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有机溶胶法制备的Pd/C催化剂对甲酸氧化的电催化性能
Electrocatalytic Performance of Pd/C Catalyst Prepared with Organic Sol Method for Oxidation of Formic Acid
【摘要】 首次用有机溶胶法制备了碳载Pd(Pd/C)催化剂.与液相还原法制备的Pd/C催化剂相比,用有机溶胶法制备的Pd/C催化剂的Pd粒子的平均粒径较小,相对结晶度较低,因此,它对甲酸氧化的电催化活性要比用液相还原法制备的好.
【Abstract】 It is for the first time to prepare the carbon supported Pd(Pd/C) catalyst with the organic sol method.Because the average size and the relative crystallinity of the Pd particles in the Pd/C catalyst prepared with the organic sol method is smaller and lower than that in the Pd/C catalyst prepared with the liquid phase reduction method,respectively,the electrocatalytic performance of the Pd/C catalyst prepared with the organic sol method for the oxidation of formic acid is higher than that of the Pd/C catalyst prepared with the liquid phase reduction method.
【关键词】 甲酸;
直接甲酸燃料电池;
碳载Pd催化剂;
有机溶胶法;
【Key words】 formic acid; direct formic acid fuel cell; carbon supported Pd catalyst; organic sol method;
【Key words】 formic acid; direct formic acid fuel cell; carbon supported Pd catalyst; organic sol method;
【基金】 国家科技部“973”基金(G2000026408);“863”基金(2003AA517060);国家自然科学基金(20373068、20433060、20573057);江苏省科技厅高新技术基金(BG2003022);江苏省高校高新技术基金(JH02-080);国家“211”工程重点资助项目
- 【文献出处】 南京师大学报(自然科学版) ,Journal of Nanjing Normal University(Natural Science) , 编辑部邮箱 ,2006年03期
- 【分类号】O643.32
- 【被引频次】11
- 【下载频次】286