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配合物Cd2(C7H4O2Cl)4(H2O)(phen)2的合成、结构及光物理性质
Synthesis,Crystal Structure and Photoluminescence of Complex: Cd2(C7H4O2Cl)4(H2O)(phen)2
【摘要】 采用水热合成方法,得到了双核Cd(II)配合物:Cd2(C7H4O2Cl)4(H2O)(phen)2.对该化合物的单晶进行X-射线衍射分析,确定了分子结构,在晶体堆积中,配合物分子以氢键形式形成1D无限结构;同时对该化合物的UV-VIS-NIR,IR和荧光光谱进行了测定和分析指认.
【Abstract】 A dinuclear complex,Cd2(C7H4O2Cl)4(H2O)(phen)2,has been hydrothermally synthesized.The structure of the complex was determined by single crystal X-ray diffraction.In the crystal,the dinuclear unit is linked into a 1D hydrogen-bonded chain.In addition,the UV-VIS-NIR,IR and fluorescence spectra of the complex were measured and analyzed.
【关键词】 双核Cd(II)配合物;
晶体结构;
光谱;
氢键;
【Key words】 dinuclear Cd(Ⅱ) complex; crystal structure; spectra; hydrogen bond;
【Key words】 dinuclear Cd(Ⅱ) complex; crystal structure; spectra; hydrogen bond;
【基金】 国家自然科学基金资助项目(90201018,20571037)
- 【文献出处】 辽宁师范大学学报(自然科学版) ,Journal of Liaoning Normal University(Natural Science Edition) , 编辑部邮箱 ,2006年04期
- 【分类号】O641.4
- 【下载频次】111