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利用高铝粉煤灰制备莫来石微晶玻璃的实验研究

Preparation of Mullite Glass-ceramics from High Alumina Fly Ash: An Experimental Study

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【作者】 刘浩马鸿文彭辉俞子俭苏双青

【Author】 LIU Hao,MA Hong-wen,PENG Hui,YU Zi-jian,SU Shuang-qing National Laboratory of Mineral Materials,China University of Geosciences,Beijing 100083,China

【机构】 中国地质大学矿物材料国家专业实验室中国地质大学矿物材料国家专业实验室 北京100083北京100083

【摘要】 以高铝粉煤灰为主要原料,采用粉末烧结法制备出莫来石微晶玻璃。X射线衍射分析显示,经1350~1550℃热处理后,制得的微晶玻璃的主晶相均为莫来石。扫描电镜分析表明,较高的温度下热处理有利于晶体的生长。微晶玻璃的理化性能如吸水率、气孔率、体积密度、抗折强度和化学稳定性,随热处理温度的不同而发生相应的变化。1500℃热处理2 h制得的微晶玻璃具有优良的理化性能,在工程和结构领域具有潜在的应用前景。

【Abstract】 The mullite glass-ceramics was prepared with high alumina fly ash as principal raw materials by powder sintering method.X-ray diffraction analysis(XRD) results show that the crystal phase of the glass-ceramics prepared by heating at temperature ranging from 1350℃ to 1550℃ was only mullite.Scanning electron microscopy(SEM) observation indicated that the heating treatment at higher temperature is favorable for the crystal growth.The physicochemical properties of glass-ceramics,such as water absorption,porosity,apparent density,bending strength and chemical stability were varied with the variation of heating treatment temperatures.The glass-ceramics prepared by heating treatment at 1500℃ for 2 hours show that it has good properties and will have attractive potentials for engineering and construction applications.

【基金】 矿物材料国家专业实验室开放基金资助项目(05002)
  • 【文献出处】 矿物岩石地球化学通报 ,Bulletin of Mineralogy, Petrology and Geochemistry , 编辑部邮箱 ,2006年04期
  • 【分类号】TQ171
  • 【被引频次】10
  • 【下载频次】346
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