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用水合肼回收电沉积铬废液中铬的工艺条件研究
Study of Process Conditions of Reclaiming Chromium from Electrodeposition Chromium Waste Liquid Using Hydrazine Hydrate
【摘要】 研究了用水合肼回收电沉积铬废液中铬的工艺条件。实验结果表明,在30℃下于25mL含铬废液中加入1.6mLH2SO4和0.8mL水合肼,8min即可使Cr(Ⅵ)还原为Cr(Ⅲ)。然后用浓氨水使Cr(Ⅲ)完全沉淀,再与H2SO4充分反应,得到Cr2(SO4)3,从而实现铬废液中铬的回收。
【Abstract】 The process conditions of reclaiming chromium from electrodeposition chromium waste liquid using hydrazine hydrate as reducing agent were studied.The experimental result showed that Cr(Ⅵ) was deoxidized to Cr(Ⅲ) at 30 ℃ in 8 min,adding 1.6 mL H2SO4 and 0.8 mL hydrazine hydrate to 25 mL chromium-containing waste liquid.Cr(Ⅲ) was deposited using concentrated ammonia water,and then was reacted with H2SO4. Cr2(SO4)3 was obtained and thereby chromium in the chromium waste liquid was reclaimed successfully.
- 【文献出处】 精细石油化工进展 ,Advances in Fine Petrochemicals , 编辑部邮箱 ,2006年04期
- 【分类号】X781.1
- 【被引频次】15
- 【下载频次】165