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氯化高锡催化酯合成的研究进展
Research Progress on Synthesis of Esters by Stannic Chloride as Catalyst
【摘要】 SnCl4·5H2O是一种稳定性好、价廉易得、催化活性高、不腐蚀设备的固体酸催化剂。通过邻苯二甲酸二丁酯、乙酸丁酯、氯乙酸异丙酯、马来酸二丁酯、肉桂酸甲酯、癸二酸二丁酯等的合成,综述了近年来SnCl4·5HO催化酯合成的研究进展,并对其发展动态进行了展望。
【Abstract】 SnCl4·5H2O is a solid acid catalyst with many advantages, such as high stability, low cost and easy availability, high catalytical activity, without eroding to equipment and so on. The development trend for the synthesis of esters by stannic chloride as catalyst in recent years were reviewed based on the synthesis of dibutyl phthalate, butyl acetate, iso-propyl chloroacetate, dibutyl maleate, methyl cinnamate and dibutyl sebacate. And its development trends were forecasted also.
【关键词】 酯;
氯化高锡;
肉桂酸;
邻苯二甲酸酐;
正丁醇;
【Key words】 ester; stannic chloride; cinnamylic acid; phthalic anhydride; n-butyl alcohol;
【Key words】 ester; stannic chloride; cinnamylic acid; phthalic anhydride; n-butyl alcohol;
【基金】 河北省科技厅项目(04213041);廊坊师范学院项目(200517)。
- 【文献出处】 精细与专用化学品 ,Fine and Specialty Chemicals , 编辑部邮箱 ,2006年07期
- 【分类号】O643.32
- 【被引频次】1
- 【下载频次】127