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糖醛酸合成方法的研究进展
Research Progress on Methods of Synthesizing Uronic Acid
【摘要】 目前糖醛酸的合成主要是以单糖为原料氧化而得。分别就糖醛酸的几种常用合成方法进行了介绍,即直接将羟甲基氧化成羧基的一步法和先将羟甲基氧化成甲酰基、再氧化成羧基的两步法。并分别讨论了几种方法的优缺点、催化剂的选择及其适用的反应条件。
【Abstract】 Uronic acid can be synthesized by oxidation of monosaccharide. Several methods applied widely for synthesizing uronic acid are introduced,such as methods of one-step process and two-step process.The method of directly oxidizing the hydroxymethyl to carboxylic group is named one-step process.And the method which is firstly oxidizing hydroxymethyl to formacyl and secondly oxidizing formacyl to carboxylic group are called two-step process.Meanwhile,the advantage and shortcoming of the methods,and selection of catalyst and the appropriate reaction condition of the methods are discussed.
- 【文献出处】 精细与专用化学品 ,Fine and Specialty Chemicals , 编辑部邮箱 ,2006年05期
- 【分类号】TQ463.2
- 【被引频次】4
- 【下载频次】230