【摘要】 利用二丁基氧化锡与2,4,6-三甲基苯甲酸反应合成了二丁基锡双(2,4,6-三甲基苯甲酸)酯,经X-射线单晶衍射方法测定了该化合物的晶体结构,属单斜晶系,空间群为P2(1)/n,晶体学参数:a=12.07(2)nm,b=9.976(10)nm,c=22.76(4)nm,β=91.60(10),°V=2739.4(17)nm3,Z=4,R1=0.0548,wR2=0.0453。在配合物中,锡原子呈六配位的畸变八面体构型。更多还原

【Abstract】 The title complex dibutyltin bis 2,4,6-trimethylbenzoate has been synthesized by the reaction of（n-Bu）₂SnO and 2,4,6-trimethylbenzoic acid.The crystal structure of the complex has been determined by X-ray diffraction.The crystal was monoclinic with space group P2（1） / n with a =12.07（2） nm,b =9.976（10）nm,c=22.76（4） nm,β=91.60（10）°,V =2739.4（17）nm³,Z= 4,R₁ =0.0548,wR₂=0.0453.In the title complex,the tin atom is rendered into six-coordination in a distorted octahedral geometry structure.更多还原