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海上围隔进行羟基杀灭赤潮生物的研究

Study on enclosure test of treating red tide with hydroxyl radical

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【作者】 白敏冬; 张芝涛; 吕吉斌; 杨波; 白希尧;

【Author】 BAI Min-dong~(1),ZHANG Zhi-tao~(1),L Ji-bin~(2),YANG Bo~(1),BAI Xi-yao~(1)(1.Environment Engineering Institute,Dalian Maritime University,Dalian 116026,China;2.Key Laboratory of Ocean Bureau of China for the Environmental Science and Engineering of Ocean Ecology,Qingdao 266061,China)

【机构】 大连海事大学物理系高气压强电场电离放电辽宁省重点实验室; 海洋生态环境科学与工程国家海洋局重点实验室; 大连海事大学物理系高气压强电场电离放电辽宁省重点实验室 辽宁大连116026; 辽宁大连116026; 山东青岛266061;

【摘要】 采用强电场电离H2O、O2方法,在分子层次上加工成高浓度羟基自由基(OH.)溶液,喷洒在有赤潮生物的海面上,当海水的羟基质量浓度达到0.68 mg/L时,致死洛氏角刺藻(Chaetoceros lorenzianus)等31种赤潮生物效率达到99.89%,致死细菌、弧菌效率达到100%,致死膝沟藻孢囊、多甲藻孢囊效率达到100%;赤潮生物叶绿素a含量低于检测方法低限值;剩余OH.分解成H2O和O2;尸体将分解成CO2、H2O和微量无机盐。从试验数据表明,OH.是治理赤潮有效可行的绿色新方法。实现了治理赤潮以及加工羟基过程的零污染、零废物排放、零残留物。

【Abstract】 Using strong ionization discharge,H2O and O2are ionized and made into OH·solution of high concentration.When this solution is sprayed on sea surface with red tide and the ratio concentration of OH·in sea water attains to 0.68 mg/L,the efficiency of killing twenty nine kinds of organisms such as Chaetoceros lorenzianus in red tide attains to 99.89%.The efficiency of killing bacterium and Vibrio attains to 100%.The efficiency of killing Gonyaulax cysts and Peridinium cysts.Cysts attains to 100%; the chlorophyll-a content of organisms in red tide is lower than the lowest limit which can be tested;the saturation DO is obviously increased;the residual OH· is decomposed into H2O and O2;the bodies are decomposed into CO2,H2O and few inorganic salts.The experimental data show that strong ionization advanced oxidation OH· is an effective and feasible green method of treating red tide which realizes zero pollution,zero waste emission and aero residua during treating red tide and producing hydroxyl radicals.

【关键词】 强电离放电; OH.; 赤潮生物;
【Key words】 strong ionization discharge; OH·; organism of red tide;
【基金】 国家自然科学重点基金资助项目(60031001);国家重大基础研究前期研究专项项目(2002CCC00900)
  • 【分类号】X55
  • 【被引频次】4
  • 【下载频次】198
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