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4-氯苯基二苯基硫六氟磷酸盐的合成
Synthesis of(4-chlorophenyl)diphenylsufonium hexafluorophosphate
【Abstract】 In this paper,4,4’-dichlorophenyliodonium hexafluorophosphate was synthesized through 4 step reactions.The target product was novel cationic photoinitiator.The structure of the compound was identified by UV,IR,（）1H-NMR,and MS.The optimal operation conditions were determined through orthogonal layout expriment.4,4’-Dichlorophenyliodonium hexafluorophosphate 4.95g（10mmol）,diphenyl sulfide 10ml（6mmol）and catalyst 3×10-4mol were reacted at 120℃ for 3 h,and the yield was 87.9%.
【关键词】 硫鎓盐:阳离子光引发剂；
正交优化；
合成；
【Key words】 sulfonium salts； cationic photoinitiator； orthogonal layout optimization； synthesis；
【Key words】 sulfonium salts； cationic photoinitiator； orthogonal layout optimization； synthesis；
- 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2006年10期
- 【分类号】O627.51
- 【下载频次】92