节点文献

配合物[Fe(OPPh34Cl2][FeCl4]的合成和晶体结构

Synthesis and crystal structure of complex [Fe(OPPh34Cl2][FeCl4]

  • 推荐 CAJ下载
  • PDF下载
  • 不支持迅雷等下载工具,请取消加速工具后下载。

【作者】 唐爱斌周健戴洁张勇刘宇卞国庆卢雯

【Author】 TANG Ai-bin~1,ZHOU Jian~(1,2),DAI Jie~(1*),ZHANG Yong~1,BIAN Guo-qing ~1,LU Wen~1(1.College of Chenistry and Chemical Engineering,Suzhou University, Suzhou 215123,China;2.Department of Chemistry and Biology,Yulin Noramal University,Yulin 537000,China)

【机构】 苏州大学化学化工学院苏州大学化学化工学院 江苏苏州215123江苏苏州215123玉林师范学院化工系广西玉林537000

【Abstract】 A Fe(Ⅲ) compex with OPPh3,[Fe(OPPh34Cl2][FeCl4],has been synthesized and characterized by elemental analysis and IRspectrum.The crystal structure of the title complex has been determined by simgle crystal X-ray diffraction techmiques.The crystal belongs to monoclinic,space group P21/c.The cell parameters are :a=13.9323(13),b=27.5290(2),c=18.2095(17),β= 104.460(2)o,V=6762.9(11)3,Z=4,DC=1.412 g/cm3,μ=0.809 mm-1,F(000)=2952,R1=0.0796 and ωR2=0.1752for 10419 observed reflections(I>2σ(I)) out of 12343 unique data.In the cations[Fe(OPPh34Cl2]+,the Fe(Ⅲ) center adopts a slight distoned octahedral geometry comprised oftwo OPPh3 oxygen atoms and two Cl-ions at the equatorial positions,and two OPPh3 oxygenatoms at the axial positions.In the anions[FeCl4]-,The Fe(Ⅲ) ion has a sIightly distortedtetrahedI.al coordination geometry and is bonded to four Cl-ions.

【基金】 南京大学配位化学重点实验室开放基金资助项目
  • 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2006年09期
  • 【分类号】O641.4
  • 【被引频次】3
  • 【下载频次】124
节点文献中: 

本文链接的文献网络图示:

本文的引文网络