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流动注射化学发光法测定丹皮酚

Determination of paeonol by a flow injection chemiluminescence method

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【作者】 李利军钟招亨陈其锋冯军孔红星吴健玲

【Author】 LI Li-jun~(1),ZHONG Zhao-heng~(2),CHEN Qi-feng~(2),FENG Jun~(2),KONG Hong-xing~(1),WU Jian-ling~(2)(1.Dept.of Biological and Chemical Engineering,Guangxi University of Technology,Liuzhou 545006,China;2.College of Chemistry and Chemical Engineering,Guangxi University,Nanning 530005,China)

【机构】 广西工学院生物与化学工程系广西大学化学与化学工程学院广西大学化学与化学工程学院 广西柳州545006广西南宁530004广西柳州545006

【Abstract】 A new flow injection chemiluminescence method for the determination of paeonol was established.The method was based on chemiluminescence reaction of paeonol with Ce(Ⅳ) in sulfuric acid condition sensitized by rhodamine 6G.The method is simple,convenient and sensitive.The linear relationship between the intensity of chemiluminescence and the concentration of paeonol is over the range of 5.0×10-7 ~1.0×10-4mol/L.The detection limit is 9.7×10-8 mol/L,the relative standard deviation is 1.8 % for 7 measurements of 1.0×10-5mol/L standard solution.This method has been successfully applied to the determination of paeonol in ointment with recovery between 98.8% and 104%,and the results were in good agreement with those obtained by UV method.

【基金】 广西青年科学基金资助项目(桂科青0135003);广西高校百名中青年学科带头人资助计划资助项目(桂教人[2002]467)
  • 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2006年07期
  • 【分类号】O657.3
  • 【被引频次】20
  • 【下载频次】131
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