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三烷基季铵盐阳离子表面活性剂的合成与性能测定
Synthesis and properties of cationic trimeric-type quaternary ammonium salt surfactant
【摘要】 用柠檬酸、十二烷基二甲基叔胺与环氧氯丙烷反应合成了柠檬酸三酯三烷基季铵盐阳离子表面活性剂。实验结果表明,在异丙醇溶剂中,反应体系在80℃,反应时间12h,产物的收率为91.5%。用红外光谱、元素分析、高效液相色谱对其结构进行了表征,通过测定其临界胶束浓度、Krafft点及泡沫性能,对产物表面活性进行了分析。
【Abstract】 A new type of citric triesters of tridodecyl triammonium(CTTTA)cationic surfactant was synthesized by citric acid,epoxy chloropropane and dodecyl dimethyl amine.In the solvent of 2-propanol,the yield of CTTTA is 91.5% while the ratio of three reactants is l:l:l,the reaction temperature is 80℃ and the reaction time is 12 hr.The structure was characterized by IR spectrum,elementary analysis,and HPLC.By measuring its cmc,krafft point and foam properties,Is surface activities were analysised.
【关键词】 柠檬酸;
三烷基季铵盐;
阳离子表面活性剂;
合成;
性能;
【Key words】 citric acid; tridodecyl triammonium; cationic surfactant; synthesis; properties;
【Key words】 citric acid; tridodecyl triammonium; cationic surfactant; synthesis; properties;
【基金】 河南省自然科学基金资助项目(2004)
- 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2006年07期
- 【分类号】TQ423
- 【被引频次】3
- 【下载频次】541