【摘要】 用乙二胺、乙酰丙酮与水杨醛反应合成了一种不对称四齿席夫碱配体(H2L)及其铜、钴、镍、锌配合物,通过元素分析、摩尔电导、红外光谱、紫外光谱、X-射线光电子能谱等手段对配体及其配合物进行了表征,并推测所有配合物均为烯醇式四配位结构,确定新配合物的组成为MC14H16N2O2(M=Cu,Co,N i,Zn)。并研究了配合物对双氧水的催化分解性能。更多还原

【Abstract】 An unsymmetrical tetradentate Schiff base ligand（H₂L）and its copper（Ⅱ）,cobalt（Ⅱ）,nickel（Ⅱ）and zinc（Ⅱ）complexes have been synthesized from the reaction of ethylenediamine,acetylacetone and salicylaldehyde and characterized by elemental analysis,molar conductance,IR,UV-VIS and XPS.A four-coordinated enol model is proposed for these complexes.The compostion of newcoordination compounds is MC₁₄H₁₆N₂O₂（M=Cu,Co,Ni,Zn）.The catalysis of these complexes to decomposition of hydrogen peroxide has also been studied.更多还原