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Dawson型磷钨钒杂多酸催化合成环己酮乙二醇缩酮

Sythesis of Cyclohexanone Ethylene Ketal Over wells-Dawson type TungstenVanadophoric Heteropolyacid

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【作者】 许招会廖维林罗年华刘德永王甡

【Author】 XU Zhao-hi,LIAO Wei-lin,LUO Nian-hua,LIU De-yong,WANG Sheng(Department of Chemistry and Chemical Engeering of Jiangxi Normal University,NanChang 330027,China)

【机构】 江西师范大学化学化工学院江西师范大学化学化工学院 江西南昌330027江西南昌330027

【Abstract】 Wells-dawson type heteropolyacid catalyst was prepared by acidification-etherization and characterized by FTIR,over which cyclohexanone ethylene ketal was synthesized from cyclohexanone to ethylene.The experiment results showed that the optimal reaction conditions are as follows:the amount of Cyclohexanone is 0.1mol,the molar ratio of Cyclohexanone to ethylene was1.0/1.5(mol/mol),catalyst amount 1.50%(pencent of the reaction stock materials).Through reaction time 2.5h,the yield of cyclohexanone ethylene katal reached over 95.0%.

【基金】 江西师范大学青年成长基金资助项目(200400322A)
  • 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2006年02期
  • 【分类号】O643.32;O624.42
  • 【被引频次】19
  • 【下载频次】288
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