【Abstract】 Two novel complexes [Cu（TATP）（L-Leu）（H₂O）]NO₃·H₂O and [Cu（TATP）L-Met)（H₂O）]NO₃·0.5H₂O（TATP=1,4,8,9-tetraazatriphenylene,L-Leu=L-Leucinate,L-Met=L-Methioninate）were synthesized and characterized by elemental analysis,molar conductivity,infrared absorption spectrum,electronic absorption spectrum and DTA-TGA.The results showed that both of the complexes had a distorted square-pyramidal geometry with two nitrogen atoms of TATP and one amino nitrogen and one carboxylate oxygen atoms of L-Leu/L-Met at the equatorial positions,and one water oxygen at the axial position.The SOD-Like activity of the complexes was determined by NBT-illumination method.The result indicated that the complexes possessed excellent SOD-like activity and showed 50% inhibition ration in the concentration of 0.355 μmol·L^-1 and 0.185 μmol·L^-1,respectively.The greater SOD-like activity of the complex[Cu（TATP）（L-Leu）（H₂O）]NO₃·H₂O may be attributed to the smaller spatial hindrance of the side-chain group of L-Met.更多还原