节点文献

Mg²⁺和Fe³⁺对反相微乳体系中胆红素钙形成的影响

Influence of Mg²⁺ and Fe³⁺ on the formation of calcium bilirubinate in reversed microemulsion

推荐 CAJ下载
PDF下载
不支持迅雷等下载工具，请取消加速工具后下载。

【Author】 SHEN Yu-hua~(1,2),XIE An-jian~(1,2),HUANG Fang-zhi~1,ZHU Jin-miao~1,HUANG La-Chun~1,Chen Long~1(1.School of Chemistry and Chemical Engineering,Anhui University,Hefei 230039,China;2.State Key Laboratory of Coordination Chemistry,Nanjing University,Nanjing 210093,China)

【机构】安徽大学化学化工学院；安徽大学化学化工学院安徽合肥230039 南京大学配位化学国家重点实验室；江苏南京210093；安徽合肥230039 南京大学配位化学国家重点实验室；安徽合肥230039；

【摘要】在反相微乳体系中制备了一系列胆红素配合物,采用红外光谱、ICP-AES和Zeta电位进行了相关的测试与表征。结果表明:铁、镁离子与钙离子共同与胆红素发生了配位作用,且促进了体系中胆红素钙的生成;铁、镁离子的加入导致了胆红素配合物颗粒在水分散体系中的稳定性降低,易聚集。更多还原

【Abstract】 A series of bilirubinate complexes were produced in reversed microemulsion and characterized by Fourier Transform Infrared Spectroscopy,Inductively Coued Plasma Atomic Emission Spectometry and Zeta potential.The results indicated that the Mg²⁺,Fe³⁺and Ca²⁺ions coordinated with bilirubin together.Mg²⁺ and Fe³⁺ accelerated the production of calcium bilirubimate.The stability of the particles of complexes bilirubinate dispersed in water due to the addition of Mg²⁺ and Fe³⁺ions into the reversed microemulsion.The complexes were easy to affregate to form precipitate.更多还原