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钙钛矿型La0.2Pb0.4Sr0.4FeO3的制备及其气敏性

Preparation of Perovskite-type La0.2Pb0.4Sr0.4FeO3 and its Gas-sensitive Properties

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【作者】 韩周祥魏剑英程青民彭辉赵玛胡季帆

【Author】 HAN Zhou-xiang,WEI Jian-ying,CHENG Qing-min,PENG Hui,ZHAO Ma,HU Ji-fan(School of Material and Chemical Engineering,Zhengzhou University of Light Industry,Zhengzhou 450002,Henan,China)

【机构】 郑州轻工业学院材料与化工学院郑州轻工业学院材料与化工学院 河南郑州450002河南郑州450002

【摘要】 采用溶胶-凝胶法首次制备出平均粒径为22.3 nm的La0.2Pb0.4Sr0.4FeO3的晶体,这种复合晶体是正交的钙钛矿型结构.通过对其导电性和气敏性的研究,发现La0.2Pb0.4Sr0.4FeO3材料是一种p型半导体材料,并且在175℃下对甲醛具有很好的气敏性.

【Abstract】 A nanocrystalline La0.2Pb0.4Sr0.4FeO3 with an average grain size about 22.3 nm was prepared by a sol-gel method.The complex crystal is of perovskite phase with orthorhombic structure.The conductivity and gas sensitivity of La0.2Pb0.4Sr0.4FeO3 were investigated.Results demonstrate that the prepared La0.2Pb0.4Sr0.4FeO3 shows a p-type semiconductor and has the best sensitivity to formaldehyde at an operating temperature of 175 ℃.

【关键词】 钙钛矿甲醛气敏性
【Key words】 perovskiteformaldehydegas-sensing
  • 【分类号】TN304
  • 【被引频次】5
  • 【下载频次】86
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