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2-十二烷基二硫代-4-苯基-1,3,4-噻二唑-5-硫酮的合成及其对铜的缓蚀性能

Synthesis of 2-Dodecyldithio-4-phenyl-1,3,4-thiadiazole-5-thione and its Corrosion Inhibition for Copper

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【作者】 曲黎段天宝张付特路培中叶文玉

【Author】 QU Li,DUAN Tian-bao,ZHANG Fu-te,LU Pei-zhong,YE Wen-yu~(*)(College of Chemistry and Chemical Engineering,Henan University,Kaifeng 475001,Henan,China)

【机构】 河南大学化学化工学院河南大学化学化工学院 河南开封475001河南开封475001

【摘要】 合成了2-十二烷基二硫代-4-苯基-1,3,4-噻二唑-5-硫酮(DPTT),用元素分析、IR1、H NMR等技术对化合物进行了结构表征.采用动态旋转挂片法考察了DPTT和苯并三唑(BTA)复配时对铜的缓蚀作用.结果表明,单一DPTT在浓度为3.0 mg/L时缓蚀效果最佳;DPTT与BTA复配使用时显示出较好的协同效应,1.0 mg/L DPTT和1.0 mg/L BTA复配时缓蚀效果最好.

【Abstract】 The novel compound of 2-dodecyldithio-4-phenyl-1,3,4-thiadiazole-5-thione(DPTT) was synthesized and confirmed by elemental analyses,IR and 1H NMR.The synergistic effect of DPTT and benzotriazole(BTA) as corrosion inhibitor for copper were investigated.The result shown that the optimal inhibition performance was attained when DPTT was used alone at a concentration of 3.0 mg/L.There existed good synergistic inhibition effect when DPTT and BTA were used together,the optimal composition for the complex inhibitor was recommended as 1.0 mg/L DPTT and 1.0 mg/L BTA.

【关键词】 噻二唑苯并三唑缓蚀剂
【Key words】 thiadiazolebenzotriazolecorrosion inhibitorcopper
  • 【分类号】TG174.4
  • 【被引频次】10
  • 【下载频次】173
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