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电结晶铜/钴纳米多层膜结构与磁性能研究

Study of Structure and Giant Magnetoresistance of Electrocrystallized Cu/Co Nanomultilayers

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【作者】 曹为民胡滢印仁和石新红曾绍海

【Author】 CAO, Wei-Min* HU, Ying YIN, Ren-He SHI, Xin-Hong ZENG, Shao-Hai (Department of Chemistry, School of Science, Shanghai University, Shanghai 200444)

【机构】 上海大学理学院化学系上海大学理学院化学系 上海200444上海200444

【摘要】 以n型Si(111)为基底,在硼酸镀液体系中采用双槽法电结晶制备Cu/Co纳米多层膜,确定了工艺条件.用扫描电镜(SEM)和X射线衍射(XRD)对纳米多层膜的结构和形貌进行了表征,显示多层膜具有良好周期性和超晶格结构.并用物性测量系统PPMS测试了不同结构Cu/Co纳米多层膜的磁性能.磁滞回线表明:不同周期数的纳米多层膜其矫顽力均较小.巨磁阻(GMR)性能与纳米多层膜结构有关.GMR值随Co磁性层厚度增长先增大后减小,有一极值;随着Cu非磁性层厚度的增加GMR值发生周期性的振荡;随周期数N的增大,GMR值先增大,在N为60时达到了90%,随着N的继续增加而减小,当达到80周期时,GMR值趋于稳定.

【Abstract】 Cu/Co Nanomultilayers were prepared on n-type Si(111) substrate by double-bath method in bo- ric acid plating solution and the technical conditions were determined. The appearance and structure of nanomultilayers were examined by SEM and XRD methods. It has been shown that the nanomultilayers had periodical and superlattice structure. The physics property measurement system was used to characterize magnetic properties of nanomultilayers. The results showed that coercivity of these nanomultilayers with different periodicities was all small. In this paper, the correlation between structure of nanomultilayers and giant magnetoresistance (GMR) was studied. The GMR value was increased and then decreased with the in- crease of Co layer thickness, while changed periodically with Cu layer thickness. With stacking number N increased, the GMR value was increased firstly and then fell. The GMR value as large as 90% was found when N was increased to 60, while N reached 80, the GMR value was constant.

【基金】 国家自然科学基金(No.20271062);上海市教委青年基金(No.02AQ83)资助项目.
  • 【文献出处】 化学学报 ,Acta Chimica Sinica , 编辑部邮箱 ,2006年01期
  • 【分类号】O484.43
  • 【被引频次】10
  • 【下载频次】267
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