【摘要】 以二苯胺和对硝基苯胺为原料,通过胺基的重氮化碘代、乌尔曼反应、硝基还原和胺基的再次重氮化碘代反应,合成得到了三芳胺类星状爆炸物中间体N,N-二苯基-4-碘代苯胺。此一系列反应条件较温和,产率较高,中间体和产物纯化处理较容易。使用核磁和质谱对其结构进行了表征,并测得它在三氯甲烷溶液中的紫外吸收光谱和晶体的光致发光光谱。更多还原

【Abstract】 Using N-phenylaniline and 4-nitroaniline as basic materials,N,N-diphenyl-4-idodeaniline was obtained through a series of reactions such as,the diazonium and iodination of amino group,Ullmann reaction,reduction of nitro group,diazonium and iodination of amino group once again.The above mentioned reactions could take place under mild conditions,the yields were high,and the products were purified easily.The structure of N,N-diphenyl-4-idodeaniline was confirmed by(()~1HNMR) and MS,its UV-Vis and photoluminescence were studied too.更多还原