【摘要】 含苯炔结构的大环(aryleneethynylenemacrocycle,AEMs)体系具有独特的性质和潜在的应用前景,在过去的数年中被广泛研究和探索。本文系统地介绍了AEMs的合成方法,包括不同关环方法、固相合成、模板合成和聚集驱动关环法等。在研究AEMs性质方面,重点介绍了它们的自组装性能。同时也介绍了AEMs在构造三维纳米结构、液晶、管状通道、主客体复合物等超分子化学领域的应用。更多还原

【Abstract】 Macrocycles composed of arylene and ethynylene units (AEMs) have attracted great interest in recent years, due to their novel properties and potential applications. The advances in syntheses of AEMs, including different cyclization methods, solid-phase synthesis, template synthesis and aggregation driven cyclization are summarized. The progress that has been achieved for self-assembly of AEMs and its applications in supramolecule chemistry, including three-dimensional nano-structures, discotic liquid crystals, extended tubular channels, guest-host complexes and porous organic solids, is also reviewed.更多还原