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含多面低聚倍半硅氧烷新型杂化聚合物的合成
The Synthesis of Novel Hybrid Polymers Containing Polyhedral Oligomeric Silsesquioxane
【摘要】 基于多面低聚倍半硅氧烷(POSS)的杂化聚合物是近年发展起来的一类新型有机/无机杂化材料,性能独特,应用前景广阔。本文综述了含POSS新型杂化聚合物的合成研究进展,涉及自由基溶液聚合、可控活性聚合、开环易位聚合、缩聚和配位聚合。
【Abstract】 Novel hybrid polymers based on polyhedral oligomeric silsesquioxane(POSS) are a new kind of organic-inorganic hybrid materials with unique properties and wide potential applications.In this paper,the advances in the preparation of POSS-containing hybrid polymers are briefly reviewed,involving free radical solution polymerization,controlled/living polymerization,open-ring metathesis polymerization,condensation polymerization and coordination polymerization.
【关键词】 多面齐聚倍半硅氧烷;
杂化聚合物;
合成;
【Key words】 polyhedral oligomeric silsesquioxane(POSS); hybrid polymer; synthesis;
【Key words】 polyhedral oligomeric silsesquioxane(POSS); hybrid polymer; synthesis;
【基金】 广东省自然科学基金项目资助(03918420003038);教育部新世纪优秀人才支持计划项目(NCET-04-0810)。
- 【文献出处】 化学进展 ,Progress in Chemistry , 编辑部邮箱 ,2006年04期
- 【分类号】O634.41
- 【被引频次】11
- 【下载频次】471