【摘要】 从电解质溶液的经典理论、半经验模型和统计力学3方面综述了电解质溶液热力学性质的研究进展,并对各种理论和模型在理论与实践方面的局限性作了相关评述。从分子、离子角度对电解质溶液的热力学性质进行研究比较,探讨了其宏观热力学性质与微观结构的相关性。展望了电解质溶液热力学理论近期研究的热点和未来的发展方向。更多还原

【Abstract】 The research advance of thermodynamic properties for electrolyte solutions is summarized from three aspects,i.e.,tradi- tional solution theory,semi-empirical model and statistical mechan- ics.The limitations of every theory and model in theory and practice are appraised.The relativity about macroscopic thermodynamic properties and microstructure of electrolyte solutions is discussed af- ter thermodynamic properties are compared from molecule and ion aspects.The recent research hotspot of thermodynamic theory and future development direction are predicted.更多还原