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含锶极低放废物处置的地球化学工程屏障研究
Geochemical Engineering Barrier for the Disposal of Very Low-Level Radioactive Waste Containing Strontium
【摘要】 为了选择合适的添加剂以提高岩土对锶的吸附能力,采用测定吸附比的方法,选择8种添加剂加入到4种基础物料中进行实验。结果表明,在①号基础物料中,加入Na2S和Na2CO3两种添加剂后,Kd值从16.5分别增加到3.07×103和2.03×103;在②号基础物料中,加入Na2S和Na2CO3后,Kd值从26.0分别增加到3.50×103和2.20×103,达到极低放废物填埋处置的屏障要求。对添加剂的屏障机制进行了探讨,认为产生SrCO3沉淀是提高吸附比的主要原因。
【Abstract】 In order to improve the adsorptive capability of soil to strontium,the appropriate eight additives and four basic materials were selected through measuring the adsorption(ratio.) The results show that the Kd value rises respectively from 16.5 to 3.07×103 and(2.03×)(103 when) Na2S and Na2CO3 were added to the No.1 basic material.So did the No.2 basic material,the Kd value rises respectively from 26.0 to 3.50×103 and 2.20×103.Therefore the addition of Na2S and Na2CO3 can meet the barrier need of very low-level radioactive’s disposal.The barrier mechanism of additive was discussed,the main factor of the adsorption ratio’s(improvement) is the formation of SrCO3.
【Key words】 strontium; very low-level radioactive waste; geochemical; addition; barrier;
- 【文献出处】 核化学与放射化学 ,Journal of Nuclear and Radiochemistry , 编辑部邮箱 ,2006年04期
- 【分类号】TL94
- 【被引频次】9
- 【下载频次】125