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生活污水中糖类测试方法研究

Analytical methods for sugars in domestic wastewater

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【作者】 黄满红李咏梅顾国维

【Author】 Huang Manhong, Li Yongmei, Gu Guowei. (State Key Laboratory of Pollution Control and Resources Reuse, School of Environmental Engineering, Tongji University, Shanghai 20092)

【机构】 同济大学环境工程学院国家污染控制与资源化重点实验室同济大学环境工程学院国家污染控制与资源化重点实验室 上海200092上海200092

【摘要】 分别用蒽酮比色、苯酚—硫酸及气相色谱法3种测试方法测试了上海市某生活小区生活污水的糖类组成。试验结果表明,蒽酮比色法测试糖类浓度的准确性与精确性优于苯酚—硫酸法,但不能得出污水中糖类的详细组成情况;与蒽酮比色法和苯酚—硫酸法相比,气相色谱法不仅能得出污水中糖类的详细组成,而且还具有较高的精密度。气相色谱法测得的生活污水中各种单糖,如木糖、甘露糖、葡萄糖、半乳糖、鼠李糖、核糖、岩藻糖的质量浓度分别为8.25、6.02、5.52、4.80、4.44、4.41、2.66mg/L。

【Abstract】 Sugars in a typical Shanghai domestic wastewater sample were measured by three methods: anthrone method, phenol sulfuric acid method and gas chromatography (GC) method. Both colorimetric methods were adequate for glucose measurements; the anthrone method was more precise and more accurate than the phenol sulfuric acid method in the sucrose recovery test runs. Although it took a rather long time to prepare the sample for GC analysis, the GC method was the only one capable of characterizing the sample’s sugar content; xylose (8.25 mg/L), mannose (6.02 mg/L), glucose (5.52 mg/L), galactose (4.80 mg/L), rhamnose (4.44 mg/L), ribose (4.41 mg/L), and fucose (2.66 mg/L) were found in the sample. The GC method was also the most precise of the three methods.

【基金】 国家自然科学资金资助项目(No.50138010;50578114)。
  • 【文献出处】 环境污染与防治 ,Environmental Pollution & Control , 编辑部邮箱 ,2006年05期
  • 【分类号】X832
  • 【被引频次】14
  • 【下载频次】404
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