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砷华生产废渣中硫的回收利用研究

A study on recovery of sulfur from arsenic production cinder

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【作者】 刘树根田学达

【Author】 Liu Shugen~1 Tian Xueda~2(1.Department of Biology and Chemistry,Panzhihua University,Panzhihua 617000;2.Department of Environmental Engineering,Xiangtan University,Xiangtan 411105)

【机构】 攀枝花学院生物与化学工程系湘潭大学环境工程系 攀枝花617000湘潭411105

【摘要】 高温下氧化焙烧细磨后的砷华生产废渣,利用软锰矿浆吸收产生的SO2气体,吸收液经净化除杂、浓缩结晶等工序可制备工业产品硫酸锰。适宜的焙烧条件如下:焙烧温度为650℃,焙烧时间为60 m in,废渣粒度为-97μm。选择合适的吸收工艺,Mn的浸出率可达96.20%,此时SO2脱除率为87.20%。

【Abstract】 The cinder from arsenic production,containing 17.39% S and 2.31% As,has been tested for recovery sulfur using oxidation-roasting,the gas produced during roasting process was absorbed by pyrolusite and manganese sulfate was prepared.The investigation has showed that the optimum conditions of roasting process were temperature 650℃,time 60 min and size-97 μm.The maximum leaching rate of Mn was up to 96.20%,and the desulfurization rate was 87.20%.

【基金】 湖南省科技厅科技计划重点资助项目(03SSY1011)
  • 【文献出处】 环境污染治理技术与设备 ,Techniques and Equipment for Environmental Pollution Control , 编辑部邮箱 ,2006年09期
  • 【分类号】X758
  • 【被引频次】2
  • 【下载频次】64
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