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基于M-估计测定高氯化工废水CODCr
DETERMINATION OF COD_ Cr IN CHEMICAL WASTEWATER CONTAINING HIGH CHLORINE BASED ON M-ESTIMATION
【摘要】 通过对照试验证明氯气校正可以去除高氯离子对CODCr测定的干扰。事实上,对于特定的高氯废水,实验发现CODCr与实际样品的Cl-含量相关。氯气校正测定的CODCr可用国标方法测定的CODCr和Cl-含量表示。分别以M估计和最小二乘建立了校准方程。进而,实验结果对于存在个别异常值的体系前者相对后者有所改善。
【Abstract】 Contrast tests have shown that chlorine calibration can eliminate the interference of high content of Cl- in the determination of COD_ Cr. In fact, so far as specific high chlorine wastewater is concerned, to it has been found that the COD_ Cr is related to Cl- content in actual samples.Making use of COD_ Cr determined by national standard method and Cl- content in wastewater samples can give expression to COD_ Cr determined by chlorine correction method. The calibration equation can be obtained with M-estimation and least square respectively.What’s more, the results of the test show that the former can be an improvement on the latter for the system with individual abnormal values.
【Key words】 chemical wastewater containing high chlorine; COD_ Cr; determination and M-estimation;
- 【文献出处】 环境工程 ,Environmental Engineering , 编辑部邮箱 ,2006年01期
- 【分类号】X78
- 【下载频次】136