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基于M-估计测定高氯化工废水CODCr

DETERMINATION OF COD_ Cr IN CHEMICAL WASTEWATER CONTAINING HIGH CHLORINE BASED ON M-ESTIMATION

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【作者】 李峰何林钰

【Author】 Li Feng He Linyu

【机构】 山东省滨州市环境保护监测站山东省滨化集团 山东256618滨州市256619

【摘要】 通过对照试验证明氯气校正可以去除高氯离子对CODCr测定的干扰。事实上,对于特定的高氯废水,实验发现CODCr与实际样品的Cl-含量相关。氯气校正测定的CODCr可用国标方法测定的CODCr和Cl-含量表示。分别以M估计和最小二乘建立了校准方程。进而,实验结果对于存在个别异常值的体系前者相对后者有所改善。

【Abstract】 Contrast tests have shown that chlorine calibration can eliminate the interference of high content of Cl- in the determination of COD_ Cr. In fact, so far as specific high chlorine wastewater is concerned, to it has been found that the COD_ Cr is related to Cl- content in actual samples.Making use of COD_ Cr determined by national standard method and Cl- content in wastewater samples can give expression to COD_ Cr determined by chlorine correction method. The calibration equation can be obtained with M-estimation and least square respectively.What’s more, the results of the test show that the former can be an improvement on the latter for the system with individual abnormal values.

  • 【文献出处】 环境工程 ,Environmental Engineering , 编辑部邮箱 ,2006年01期
  • 【分类号】X78
  • 【下载频次】136
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