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二元有机小分子混合物在聚乙烯中的共溶

Co-solubility of binary low-molecules in polyethylene

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【作者】 姚文娟胡晓萍阳永荣

【Author】 YAO Wenjuan,HU Xiaoping,YANG Yongrong (Unilab Research Center of Chemical Reaction Engineering,Zhejiang University, Hangzhou 310027,Zhejiang,China)

【机构】 浙江大学联合化学反应工程研究所浙江大学联合化学反应工程研究所 浙江杭州310027浙江杭州310027

【Abstract】 Solubility data for the ternary system ethylene/iso-pentane/PE and ethylene/n-hexane/PE were determined for PE crystallinity 48.6% at temperatures of 70—90℃ and pressures up to 2MPa with the partial pressures of iso-pentane 80—190 kPa and those of hexane 20—90 kPa.Compared with the solubility data of the binary system, the effects of the ternary system were discussed with respect to the partial pressure of the second component and temperature.It was shown that as the results of dilation and interaction between low-molecules, the presence of iso-pentane or n-hexane gave rise to an increase in the solubility of ethylene whereas the presence of ethylene decreased the solubility of iso-pentane or n-hexane.The higher the partial pressure of the second component, the more the impact on the solubility of the first one.The impact increased with decreasing temperature and increasing partial pressure of the first component.The solubility of ethylene in the ternary system could be described by Henry’s law whichwas similar to the binary system. Flory-Huggins model was satisfactory for fitting solubility data of both iso-pentane and n-hexane, especially the former.

【关键词】 聚乙烯乙烯正己烷异戊烷溶解度
【Key words】 polyethyleneethylenehexaneiso-pentanesolubility
  • 【文献出处】 化工学报 ,Journal of Chemical Industry and Engineering(China) , 编辑部邮箱 ,2006年05期
  • 【分类号】TQ325.12
  • 【被引频次】1
  • 【下载频次】59
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