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热处理对Ti18Cr24V55Zr3合金吸放氢性能的影响

Effects of heat treatment on hydriding/dehydriding characteristics of Ti18Cr24V55Zr3 alloy

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【作者】 陈立新刘剑王新华郑坊平陈长聘

【Author】 CHEN Lixin,LIU Jian,WANG Xinhua,ZHENG Fangping,CHEN Changpin(College of Materials Science and Chemical Engineering,Zhejiang University,Hangzhou 310027,Zhejiang,China)

【机构】 浙江大学材料与化学工程学院浙江大学材料与化学工程学院 浙江杭州310027浙江杭州310027

【Abstract】 The effects of heat treatment(at 1473 K for 2 h or 6 h) on the hydriding/dehydriding characteristics of Ti18Cr24V55Zr3 alloy were investigated.The microstructure analysis showed that the as-cast alloy consisted of a V-based solid solution main phase with BCC structure and a ZrCr2 secondary phase,and the alloys treated at 1473 K for 2 h and 6 h had a small amount of Ti-rich phase besides the V-based solid solution and ZrCr2 phase.It was found that the heat treatment led to an increase of the kinetics of the alloy and a slight decrease of the hydrogen absorption capacity at 20℃.However,the heat treatment increased the width and decreased the gradient of the plateau of the p-c isotherm.The result showed that the alloy treated at 1473 K for 2 h had good overall properties,such as activation behavior of 1 cycle,hydrogen absorption capacity of 394 ml·g-1 at 20℃ and effective desorption capacity of 232 ml·g-1 at 80℃.

【基金】 国家高技术研究与发展计划项目(2003AA515021);国家自然科学基金项目(50271064,50571089)~~
  • 【文献出处】 化工学报 ,Journal of Chemical Industry and Engineering(China) , 编辑部邮箱 ,2006年03期
  • 【分类号】TG139.7
  • 【被引频次】3
  • 【下载频次】110
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