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负载钌的HMS催化剂催化氧化醇

Aerobic oxidation of alcohols catalyzed by supported Ru/HMS zeolite

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【作者】 纪红兵钱宇王婷婷张美英

【Author】 JI Hongbing~1,QIAN Yu~1,WANG Tingting~1,ZHANG Meiying~2(~1 School of Chemical Engineering,~2 Analytical Testing Center,South China University of Technology,Guangzhou 510640,Guangdong,China)

【机构】 华南理工大学化工学院华南理工大学测试中心 广东广州510640

【Abstract】 Supported Ru/HMS zeolite was prepared via the impregnation method.Characterization results showed that HMS was partially covered by ruthenium on its surface,and the degree of irregularity on the catalyst surface was increased.Thus,specific surface area and pore volume of this catalyst were also increased.The Ru/HMS catalyst exhibited efficient catalytic performance towards liquid-phase oxidation of allylic and benzylic alcohols under mild conditions in the presence of molecular oxygen.

【关键词】 HMS分子筛催化氧化
【Key words】 rutheniumHMS zeolitecatalytic oxidationalcohols
【基金】 国家自然科学基金项目(20306009,20576045,20225620)~~
  • 【文献出处】 化工学报 ,Journal of Chemical Industry and Engineering(China) , 编辑部邮箱 ,2006年03期
  • 【分类号】O643.36
  • 【被引频次】17
  • 【下载频次】325
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