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纳米炭黑填充的Lyocell纤维的结构与性能

Structure and properties of nano-carbon black filled Lyocell fiber

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【作者】 张慧慧郭利伟邵惠丽胡学超

【Author】 Zhang Huihui, Guo Liwei, Shao Huili, Hu Xuechao (State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Material Science and Engineering, Donghua University, Shanghai 200051)

【机构】 东华大学材料学院纤维材料改性国家重点实验室东华大学材料学院纤维材料改性国家重点实验室 上海 200051上海 200051

【摘要】 研究了纳米炭黑在Lyocell纺丝溶液中的分散性,制备不同含量纳米炭黑填充的Lyocell纤维,分析了纤维的结构与性能。结果表明:纳米炭黑在Lyocell纺丝溶液中具有良好的分散性;所得的纤维仍然具有纤维素Ⅱ晶型的结构,同时还保留了纳米炭黑的特征衍射峰;填充了纳米炭黑的纤维力学性能略有降低,但热稳定性不变;SEM结果表明纳米炭黑填充的Lyocell纤维表面光滑且截面为圆形,结构更加致密。

【Abstract】 The dispersity of nano-carbon black in Lyocell spinning solution was studied. The Lyocell fibers filled with different amounts of nano-carbon black were prepared. The structure and properties of the obtained fiber were analyzed. The results showed that the nano-carbon black can be dispersed very well in Lyocell spinning solution. The obtained fibers had celluloseⅡcrystal structure and kept the characteristic peak of carbon black at the same time. The mechanical properties of nano-carbon black filled Lyocell fiber decreased slightly but the heat stability remained unchanged. The SEM results showed that the nano-carbon black filled Lyocell fiber had a smooth surface and circular cross section with a compacter structure.

【基金】 国家自然科学基金资助项目(20074005);上海市优秀学科带头人计划项目(05XD14025);上海市重点学科建设项目
  • 【文献出处】 合成纤维工业 ,China Synthetic Fiber Industry , 编辑部邮箱 ,2006年06期
  • 【分类号】TQ340.7
  • 【被引频次】2
  • 【下载频次】101
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