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PVA水溶纤维的结构与力学性能的关系

Relationship between structure and mechanical properties of water-soluble PVA fiber

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【作者】 徐建军李守群叶光斗何云李黎王志金

【Author】 Xu Jianjun, Li Shouqun, Ye Guangdou, He Yun, Li Li, Wang Zhijin (College of Polymer Science and Engineering, Sichuan University, Chengdu 610065; Sichuan Vinylon Works, Chongqing 401254)

【机构】 四川大学高分子科学与工程学院四川维尼纶厂四川维尼纶厂 四川 成都 610065四川 成都 610065四川 重庆 401254

【摘要】 通过甲醇溶剂冻胶纺丝制备水溶温度为5-80℃聚乙烯醇(PVA)水溶纤维,采用X射线衍射、双折射、电子强伸仪等测定了PVA水溶纤维的结晶度、取向度、应力应变曲线。讨论了PVA水溶纤维的结构与力学性能的关系。结果表明:纤维的结晶度和取向度随拉伸倍数的增加而增加,拉伸倍数为16时,纤维力学性能良好,纤维结构均匀,水溶温度范围宽。

【Abstract】 The polyvinyl alcohol (PVA) fiber water-soluble at 5 - 80℃ was prepared with methyl alcohol as a solvent by gel spinning. The crystallinity, orientation degree and stress-strain curves were measured by X-ray diffraction, birefringence method and electron tensile strength test. The relationship between the structure and mechanical properties of water-soluble PVA fiber was discussed. The result showed that the crystallinity and orientation degree were increased while increasing draw ratio. The PVA fiber had a uniform structure, good mechanical properties and a wide water-soluble temperature range at the draw ratio of 16.

【基金】 中国石化集团公司资助项目(03H184)。
  • 【文献出处】 合成纤维工业 ,China Synthetic Fiber Industry , 编辑部邮箱 ,2006年02期
  • 【分类号】TQ340.1
  • 【被引频次】2
  • 【下载频次】355
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