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对位芳纶短纤维/氢化丁腈橡胶复合材料的制备及其结构性能

Preparation, structure and properties of short para aramid fiber/ hydrogenated nitrile-butadiene rubber composites

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【作者】 任玉柱冯予星李世民钦焕宇张立群

【Author】 Ren Yuzhu1, Feng Yuxing1, Li Shimin2, Qin Huanyu3, Zhang Liqun1(1. Key Laboratory of Beijing City for Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing 100029, China; 2. Oil Production Engineering and Technology Institute of Zhongyuan Petroleum Exploration Bureau, Puyang 457001, China; 3. Heilongjiang Fujin Rubber Co Ltd, Fujin 156100, China)

【机构】 北京化工大学北京市新型高分子材料制备与成型加工重点实验室中原油田采油工程技术研究院黑龙江富锦市橡胶有限责任公司北京化工大学北京市新型高分子材料制备与成型加工重点实验室 北京100029北京100029河南濮阳457001黑龙江富锦156100

【摘要】 采用综合性能优异的氢化丁腈橡胶(HNBR)和耐高温对位芳纶短纤维复合,制备了高强度、高模量和耐高温的复合材料,比较了芳纶短纤维类型、纤维用量等对复合材料力学性能和流变行为的影响。结果表明,芳纶浆粕(PPTA-pulp)比芳纶短切纤维(DCF)对橡胶有更佳的增强效果,二者都能明显提高HNBR的高温强度,但PPTA-pulp的效果更为明显。PPTA-pulp增强橡胶复合材料的挤出物外观性能也较DCF增强橡胶复合材料好。

【Abstract】 Hydrogenated nitrile-butadiene rubber with excellent comprehensive properties was reinforced by-powered para aramid. The composites showed high tensile strength, high modulus and high temperature resistance. Mechanical and rheological properties influenced by kinds and contents of fibers were researched. It was proved that aramid pulp ( PPTA-pulp) had better effect on reinforcing the composites than dipped chopped fibers(DCF). They were both elevating the high temperature strength of composites, but PPTA-pulp was more effective. More over, extrudate of the composites reinforced by PPTA-pulp was more smooth than that of DCF.

【基金】 国家“863”基金资助项目(2003AA333060
  • 【文献出处】 合成橡胶工业 ,China Synthetic Rubber Industry , 编辑部邮箱 ,2006年02期
  • 【分类号】TQ333.7
  • 【被引频次】29
  • 【下载频次】416
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