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温度对以二乙基亚磷酸酯为给电子体的铁系催化剂聚合异戊二烯的影响(英文)

Effect of temperature on polymerization of isoprene using ironbased catalysts with diethyl phosphite as an electron donor

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【Author】 Guo Yu~ 1,2 , Hu Yanming~ 1,2 , Zhang Xuequan~ 1* ,Dong Weimin~1, Jiang Liansheng~1(1.Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;2.Graduate School of Chinese Academy of Sciences, Beijing 100039,China)

【机构】中国科学院长春应用化学研究所；中国科学院长春应用化学研究所吉林长春130022；中国科学院研究生院；北京100039；吉林长春130022；

【摘要】 Iron-based catalysts for polymerization of isoprene have not been ex-tensively studied. Those catalysts combined with bidentate nitrogencompound as an electron donor are able to polymerize isoprene to af-ford polymer having high mass fraction of3,4-unit(more than 70%),while the polymer yields eviden更多还原

【关键词】催化剂体系；给电子体； polymerization；亚磷酸酯；二乙基；异戊二烯；催化活性；乙酰丙酮铁； tempera；铁系；

【文献出处】合成橡胶工业 ,China Synthetic Rubber Industry , 编辑部邮箱 ,2006年01期

【分类号】O643.32;O631.5
【下载频次】103

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