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一种离子型超分子液晶的合成及其液晶性研究
Synthesis of a Kind of Ionic Supramolecule Liquid Crystals and Their Liquid Crystalline Properties
【摘要】 以对羟基联苯腈为原料,合成了N,N-二乙基-N-甲基-6-(4′-氰基联苯氧基)己基碘化铵(WQ),不具液晶性的WQ分别与聚丙烯酸钠和聚2-丙烯酰胺基-2-甲基丙磺酸钠在乙醇-水体系中通过自组装形成复合物,这些复合物表现出液晶性。通过DSC,POM和XRD对复合物的液晶性进行了研究。
【Abstract】 N,N-diethyl-N-methyl-6-(4′-cyanobiphenoxyl)hexylammonium iodide(WQ) was synthesized from 4-cyano-4′-hydroxybiphenyl.The complexes,which were prepared by WQ with poly(arcy sodium) or poly(2-arcylamido-2-methylpropane sulfate sodium) in a ethanol-water system by self-assembly,exhibit liquid crystalline properties.The characteristic performance and texture of supramolecule liquid crystals were determined by DSC,POM and XRD.
- 【文献出处】 合成化学 ,Chinese Journal of Synthetic Chemistry , 编辑部邮箱 ,2006年06期
- 【分类号】O753.2
- 【被引频次】12
- 【下载频次】394