【摘要】 以2,3-二氰基-1,4-二硫杂环己烯为原料,钼酸铵为催化剂,在七水硫酸亚铁存在(或不存在)下,用干熔法合成了四-(对-二硫杂环己烯)-四氮杂卟啉铁配合物[FePz(dtn)4]和它的自由配体[H2Pz(dtn)4],产率分别为81.3%和80.2%。FePz(dtn)4和H2Pz(dtn)4的结构经UV-V is,IR,元素分析和X-射线光电子能谱表征。更多还原

【Abstract】 A complex of iron（Ⅱ） tetra-（1,4-dithiacyclohexene）-porphyrazine[FePz（dtn）₄] and its free-base[H₂Pz（dtn）₄]were synthesized from 2,3-dicyano-1,4-dithiacyclohexene by solid-melted method using ammonium molybdate as a catalyst in the presence of ferrous sulfate heptahydrate（or no）.The yields were up to 81.3% and 80.2%,respectively.The structures of FePz（dtn）₄ and H₂Pz（dtn）₄ were characterized by UV-Vis,IR,elemental analysis and X-ray photoemission spectra.更多还原