【摘要】 采用无溶剂微波固相法,合成了meso-苯基四苯并卟啉锌(Zn-PnTBP,n=1,2,3,4),通过紫外-可见光谱表征了其结构。结果表明原料配比、研磨时间、微波辐射时间等对反应的主要产物和产率都有很大影响,最终确定了形成Zn-PnTBP的最佳条件:n(邻苯二甲酰亚铵)∶n(苯乙酸)∶n(乙酸锌)=1.0∶1.4∶0.8、研磨时间为5 min,在中等微波辐射下反应13 min,产率达到28%。更多还原

【Abstract】 meso-Phenyl substituted tetrabenzoporphyrinato-zinc(Zn-P_nTBP) were prepared by microwave irradiating on the reactant mixture of phthalimide,phenylacetic acid and zinc acetate.The products were characterized by UV-Vis determination.Experimental results indicated that the ratio of reactants,grinding time and microwave irradiation time had great influence on the main product and its yield.The optimum conditions for Zn-P_nTBP were determined in the end.更多还原