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絮凝沉降的温度效应

The Effect of Temperature on Flocculation Settling

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【作者】 林倩曾祥饮刘定富王国海

【Author】 LIN Qian,ZENG Xiang-qin,LIU Ding-fu,WANG Guo-hai (College of chemistry,Guizhou University,Guizhou Guiyang 550003,China)

【机构】 贵州大学化学工程学院贵州大学化学工程学院 贵州贵阳550003贵州贵阳550003

【摘要】 用传统的化学动力学方法讨论了温度对絮凝过程的影响,测定了木质素溶液在不同温度时被聚氯化铝铁(PAFC)絮凝的絮凝沉降曲线,讨论了曲线上拐点的意义,并估算出该胶体溶液絮凝时的活化能,它相当于DLVO理论为胶体粒子间的势能能垒φm,实验得出φm≈16.5kT

【Abstract】 The effect of temperature on flocculation settling process was discussed in the view of the traditional chemical kinetics.Moreover,the flocculation settlement curves of the lignin locution were determined at deferent temperatures under the condition of the polyaluminum ferric chloride flocculation,the sense of the inflexion point of the curve was discussed,and the acaivation energy of the colloid solution flocculatiov was eltimated,which corresponds to the potential-energy(Φm) between sol particles according to DLVO theory.The(Φm) was given about 16.5KT through experiment.

【关键词】 絮凝拐点温度势能能垒胶体
【Key words】 flocculationinflexion pointtemperaturepotential-energy barriercolloid
【基金】 贵州省科学技术基金((96)1603)
  • 【文献出处】 贵州大学学报(自然科学版) ,Journal of Guizhou University(Natural Science Edition) , 编辑部邮箱 ,2006年03期
  • 【分类号】O648.14
  • 【被引频次】9
  • 【下载频次】254
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